置換キノイド化合物（置換キノジメタン化合物、置換キノンメチド化合物、置換キノンメチドイミン化合物）の結晶や共結晶の結晶構造解析とそれらの固相重合反応生成物の解析を基に結晶中における分子間相互作用と固相重合反応性との関係を明らかにした。また、種々の置換キノンメチド化合物を合成し、それらの固相重合と溶液重合を行い生成ポリマーの一次構造制御について議論した。
Substituted quinoid compounds (substituted quinodimethanes, substituted quinone methides, substituted quinone methide imines) crystals and their cocrystals were prepared, and the relationship of the solid-state polymerization reactivity with the intermolecular interaction between molecules in the crystals was discussed on the basis of their single-crystal structure analyses and their products obtained by solid-state polymerizations. And also, novel substituted quinone methides were prepared, and their solid-state and solution polymerizations were investigated and control of the primary structure of obtained polymers was discussed.
内容記述
2010年度～2012年度科学研究費補助金(基盤研究(C))研究成果報告書
発行年
2013-04-24
フォーマット
application/pdf
著者版フラグ
publisher
その他のタイトル
Solid-State Polymerization and Structure Control Based on Quinoid Compounds
キノイド化合物を利用した固相重合反応と構造制御
40K17146.pdf
(339.06KB)
