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Phototransformed C_<60> Powder and Film Synthesized in Toluene, Benzene and Carbon Disulfide Solvents TAKAHASHI, Yutaka 高橋, 裕 OHTA, Toshihiko 太田, 俊彦 KOTAKE, Shigeo 小竹, 茂夫 MATUMURO, Akihito 松室, 昭仁 SENOO, Masafumi 妹尾, 允史 社団法人日本セラミックス協会 本文データは学協会の許諾に基づきCiNiiから複製したものである 570 Fullerence Solution Toluene Benzene Carbon disulfide Ultraviolet light Photopolymerization application/pdf C_<60> dissolved in toluene, benzene and carbon disulfide respectively, yielded a brown precipitate upon exposure to ultraviolet radiation. A thin film was deposited on a silicon substrate when dipped in each of the solutions. Further examination of this deposit revealed: (1) the substance to be amorphous by TEM observation; (2) No oxygen was detected by Auger electron spectroscopy; (3) Absorption peaks produced by FT-IR differed from those of pristine C_<60> solid-state photopolymerized C_<60> and high-pressure polymerized C_<60>: (4) The same substance was obatained for each of the three solvents; (5) The substance obtained is presumably a new photopolymerized C_<60> solid. 日本セラミックス協会 1997-06-01 eng journal article VoR http://hdl.handle.net/10076/8511 https://mie-u.repo.nii.ac.jp/records/8192 http://ci.nii.ac.jp/naid/110002289203/ AN10040326 0914-5400 日本セラミックス協会学術論文誌 105 1222 544 547 https://mie-u.repo.nii.ac.jp/record/8192/files/40A6630.pdf application/pdf 1.0 MB 2017-02-18