{"created":"2023-06-19T11:41:21.275366+00:00","id":10088,"links":{},"metadata":{"_buckets":{"deposit":"4884e800-ef06-46a4-988f-032fbad7a30e"},"_deposit":{"created_by":15,"id":"10088","owners":[15],"pid":{"revision_id":0,"type":"depid","value":"10088"},"status":"published"},"_oai":{"id":"oai:mie-u.repo.nii.ac.jp:00010088","sets":["366:680:1692684999689"]},"author_link":[],"item_8_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2013-04-24","bibliographicIssueDateType":"Issued"}}]},"item_8_description_14":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_8_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"マンガンイオンを触媒活性中心に含む金属酵素の一つに、水２分子の酸素１分子への４電子酸化を触媒する酵素の中に酸素発生複合体(OEC)がある。OECは葉緑体の中にあり光合成の一部を担っている。OECによる触媒機構はまったく解明されておらず、実験と理論の両面から精力的に研究がなされている。我々は理論化学計算から、Kokサイクルとして提案されている五つの酸化状態であるS0, S1, S2, S3, S4の各状態の分子構造と電子状態を決定し、触媒機構を提案した。これによって、次世代のエネルギー源である酸素と水素を水分子から生成する装置開発へと繋がっていくことが期待される。","subitem_description_type":"Abstract"},{"subitem_description":"Oxygen-Evolving Complex (OEC), which is one of metalloenzymes including manganese ions at active site, catalyzes four-electron oxidation of two water molecules to give oxygen. The catalytic mechanism of OEC is unclear and has been investigated intensively based on theoretical and experimental viewpoints. We have determined the molecular and electronic structures of five oxidative states, S0, S1, S2, S3, and S4 proposed as Kok cycle using theoretical study. We have also proposed the catalytic mechanism. It is expected that our results will be basis to develop a new unit producing oxygen and hydrogen as next-generation energy.","subitem_description_type":"Abstract"}]},"item_8_description_5":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"2010年度～2012年度科学研究費補助金(基盤研究(C))研究成果報告書","subitem_description_type":"Other"}]},"item_8_description_64":{"attribute_name":"科研費番号","attribute_value_mlt":[{"subitem_description":"22550010","subitem_description_type":"Other"}]},"item_8_publisher_30":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"三重大学"}]},"item_8_text_18":{"attribute_name":"その他のタイトル","attribute_value_mlt":[{"subitem_text_value":"Theoretical Study on Catalytic Mechanism of Metalloenzyme including Manganese Ions at Active Site"}]},"item_8_text_65":{"attribute_name":"資源タイプ（三重大）","attribute_value_mlt":[{"subitem_text_value":"Kaken / 科研費報告書"}]},"item_8_version_type_15":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"吉岡, 泰規","creatorNameLang":"ja"},{"creatorName":"YOSHIOKA, YASUNORI","creatorNameLang":"en"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2017-02-20"}],"displaytype":"detail","filename":"40K17144.pdf","filesize":[{"value":"424.4 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"40K17144.pdf","url":"https://mie-u.repo.nii.ac.jp/record/10088/files/40K17144.pdf"},"version_id":"5ebff569-8c6f-4b27-9e12-9bbc4fe960b9"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"生物物理科学","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"research report","resourceuri":"http://purl.org/coar/resource_type/c_18ws"}]},"item_title":"マンガンイオンを活性中心に含む金属酵素の触媒機構に関する理論的研究","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"マンガンイオンを活性中心に含む金属酵素の触媒機構に関する理論的研究","subitem_title_language":"ja"}]},"item_type_id":"8","owner":"15","path":["1692684999689"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2014-12-18"},"publish_date":"2014-12-18","publish_status":"0","recid":"10088","relation_version_is_last":true,"title":["マンガンイオンを活性中心に含む金属酵素の触媒機構に関する理論的研究"],"weko_creator_id":"15","weko_shared_id":-1},"updated":"2023-11-17T01:41:54.823381+00:00"}