{"created":"2023-06-19T11:41:21.865441+00:00","id":10102,"links":{},"metadata":{"_buckets":{"deposit":"7f126925-85ae-49eb-9ff8-62dc74dcab66"},"_deposit":{"created_by":15,"id":"10102","owners":[15],"pid":{"revision_id":0,"type":"depid","value":"10102"},"status":"published"},"_oai":{"id":"oai:mie-u.repo.nii.ac.jp:00010102","sets":["366:680:1692684999689"]},"author_link":[],"item_8_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2013-04-26","bibliographicIssueDateType":"Issued"}}]},"item_8_description_14":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_8_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"アルキニルイミンから調製したイミノシクロブテノンのキラルリン酸を触媒に用いる不斉還元反応により、キラルなアミノシクロブテノンを高エナンチオ選択的に得られることを見出した。また、得られたアミノシクロブテノンの熱的転位反応において、適切なアミンを用いることによって、キラルなcis-およびtrans-β-ラクタムの選択的合成に成功した。さらに、イミノシクロブテノンの熱的転位反応により、4-キノロンが高収率で得られることも見出した。","subitem_description_type":"Abstract"},{"subitem_description":"Chiral phosphoric acid catalyzed enantioselective reduction of iminocyclobutenones prepared from alkynyl imines was carried out to give the chiral aminocyclobutenones with high enantioselectivities. Thermal rearrangement of chiral aminocyclobutenones in the presence of appropriate amines proceeded to afford the chiral cis- or trans-β-lactams with high diastereo- and enantioselectivities, respectively. Moreover, thermal rearrangement of iminocyclobutenones gave the 4-quinolones in high yields.","subitem_description_type":"Abstract"}]},"item_8_description_5":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"2010年度～2012年度科学研究費補助金(基盤研究(C))研究成果報告書","subitem_description_type":"Other"}]},"item_8_description_64":{"attribute_name":"科研費番号","attribute_value_mlt":[{"subitem_description":"22550096","subitem_description_type":"Other"}]},"item_8_publisher_30":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"三重大学"}]},"item_8_text_18":{"attribute_name":"その他のタイトル","attribute_value_mlt":[{"subitem_text_value":"Synthetic Study of Nitrogen Containing Compounds Based on New Reaction Mechanisms Using Alkynyl Imines as Starting Materials"}]},"item_8_text_65":{"attribute_name":"資源タイプ（三重大）","attribute_value_mlt":[{"subitem_text_value":"Kaken / 科研費報告書"}]},"item_8_version_type_15":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"八谷, 巌","creatorNameLang":"ja"},{"creatorName":"HACHIYA, IWAO","creatorNameLang":"en"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2017-02-20"}],"displaytype":"detail","filename":"40K17145.pdf","filesize":[{"value":"358.0 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"40K17145.pdf","url":"https://mie-u.repo.nii.ac.jp/record/10102/files/40K17145.pdf"},"version_id":"49687c11-146d-4231-a951-f8e317137f52"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"β-ラクタム","subitem_subject_scheme":"Other"},{"subitem_subject":"含窒素化合物","subitem_subject_scheme":"Other"},{"subitem_subject":"シクロブテノン","subitem_subject_scheme":"Other"},{"subitem_subject":"不斉還元","subitem_subject_scheme":"Other"},{"subitem_subject":"イミン","subitem_subject_scheme":"Other"},{"subitem_subject":"ケチミン","subitem_subject_scheme":"Other"},{"subitem_subject":"キラルリン酸","subitem_subject_scheme":"Other"},{"subitem_subject":"共役付加反応","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"research report","resourceuri":"http://purl.org/coar/resource_type/c_18ws"}]},"item_title":"アルキニルイミンを出発物質に用いる新規反応機構を基軸とする含窒素化合物の合成研究","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"アルキニルイミンを出発物質に用いる新規反応機構を基軸とする含窒素化合物の合成研究","subitem_title_language":"ja"}]},"item_type_id":"8","owner":"15","path":["1692684999689"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2014-12-18"},"publish_date":"2014-12-18","publish_status":"0","recid":"10102","relation_version_is_last":true,"title":["アルキニルイミンを出発物質に用いる新規反応機構を基軸とする含窒素化合物の合成研究"],"weko_creator_id":"15","weko_shared_id":-1},"updated":"2023-11-17T01:42:23.954976+00:00"}