{"created":"2023-06-19T11:41:22.575796+00:00","id":10119,"links":{},"metadata":{"_buckets":{"deposit":"9746aab0-b4dd-463e-8140-0407b37c1ec0"},"_deposit":{"created_by":15,"id":"10119","owners":[15],"pid":{"revision_id":0,"type":"depid","value":"10119"},"status":"published"},"_oai":{"id":"oai:mie-u.repo.nii.ac.jp:00010119","sets":["366:680:1692685139729"]},"author_link":["25161","25162","25163"],"item_8_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2015-05-18","bibliographicIssueDateType":"Issued"}}]},"item_8_description_14":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_8_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"現在pH電極に用いられているLi伝導型のガラス電極には、汚れの蓄積により容易にpH応答が低下するという致命的な問題がある。この問題を解決するために、本研究では2つのタイプのメンテナンスフリーの電子伝導型pH応答ガラスを開発した。一つは、セルフクリーニング特性(光触媒活性と光誘起親水性)を有するTi3+を含有するTi02-P205（TP）ガラスである。もう一つは、防汚特性（撥水性）を有するFe203-Bi203-B203(FeBiB)ガラスである。これらのガラスは、レアメタルであるLiを使用せずに従来通りの高いpH感度を実現しつつ、従来とは異なる電子伝導を利用することで高速pH応答を実現した。","subitem_description_type":"Abstract"},{"subitem_description":"Commercially available pH electrodes (Li20-Si02-based glasses) have fatal problem that pH response is deteriorated by the accumulation of stain easily. In order to solve this problem, we developed two types of maintenance-free pH responsive glasses. The first one is Ti3+-containing Ti02-P205 (TP) glasses with self-cleaning property (photocatalytic activity and photo-induced hydrophilicity). The second one is Fe203-Bi203-B203 (FeBiB) glasses with anti-fouling property (hydrophobicity). In addition, we found that TP and FeBiB glasses show the quick pH response based on the electronic conduction as well as the high pH sensitivity.","subitem_description_type":"Abstract"}]},"item_8_description_5":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"2012年度～2014年度科学研究費補助金(基盤研究(C))研究成果報告書","subitem_description_type":"Other"}]},"item_8_description_64":{"attribute_name":"科研費番号","attribute_value_mlt":[{"subitem_description":"24560823","subitem_description_type":"Other"}]},"item_8_publisher_30":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"三重大学"}]},"item_8_text_18":{"attribute_name":"その他のタイトル","attribute_value_mlt":[{"subitem_text_value":"Development of Li-free self-cleaning glasses with quick pH response"}]},"item_8_text_65":{"attribute_name":"資源タイプ（三重大）","attribute_value_mlt":[{"subitem_text_value":"Kaken / 科研費報告書"}]},"item_8_version_type_15":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"橋本, 忠範","creatorNameLang":"ja"},{"creatorName":"HASHIMOTO, Tadanori","creatorNameLang":"en"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"石原, 篤","creatorNameLang":"ja"},{"creatorName":"ISHIHARA, Atsushi","creatorNameLang":"en"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"那須, 弘行","creatorNameLang":"ja"},{"creatorName":"NASU, Hiroyuki","creatorNameLang":"en"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2017-02-20"}],"displaytype":"detail","filename":"40K17858.pdf","filesize":[{"value":"592.6 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"40K17858.pdf","url":"https://mie-u.repo.nii.ac.jp/record/10119/files/40K17858.pdf"},"version_id":"9bbef193-94a5-4026-92ce-6080885e97c4"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"pH応答ガラス","subitem_subject_scheme":"Other"},{"subitem_subject":"Liフリー","subitem_subject_scheme":"Other"},{"subitem_subject":"電子伝導ガラス","subitem_subject_scheme":"Other"},{"subitem_subject":"メンテナンスフリー","subitem_subject_scheme":"Other"},{"subitem_subject":"光触媒活性","subitem_subject_scheme":"Other"},{"subitem_subject":"光誘起親水性","subitem_subject_scheme":"Other"},{"subitem_subject":"撥水性","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"research report","resourceuri":"http://purl.org/coar/resource_type/c_18ws"}]},"item_title":"Ｌｉを使用しない高速ｐＨ応答型のセルフクリーニングガラスの開発","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Ｌｉを使用しない高速ｐＨ応答型のセルフクリーニングガラスの開発","subitem_title_language":"ja"}]},"item_type_id":"8","owner":"15","path":["1692685139729"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2017-01-13"},"publish_date":"2017-01-13","publish_status":"0","recid":"10119","relation_version_is_last":true,"title":["Ｌｉを使用しない高速ｐＨ応答型のセルフクリーニングガラスの開発"],"weko_creator_id":"15","weko_shared_id":-1},"updated":"2023-11-17T02:34:00.756563+00:00"}