@techreport{oai:mie-u.repo.nii.ac.jp:00011765,
 author = {石原, 篤 and ISHIHARA, Atsushi and 那須, 弘行 and NASU, Hiroyuki and 橋本, 忠範 and HASHIMOTO, Tadanori},
 month = {May},
 note = {application/pdf, ゲル骨格補強法大細孔径シリカと二層の階層構造を有するゼオライト含有シリカ-アルミナとを組み合わせることにより、新しいミクロ-メソ-メソの三層構造を有する触媒を調製し、その触媒反応特性を明らかにした。これを用いた油脂の接触分解を検討した結果、原料の2層構造触媒よりも高活性が得られた。ヘキサメチルジシロキサンと無水酢酸の組み合わせが有効であり、焼成後細孔容積5cm3/g、細孔径40nmの大きな細孔を持つシリカを得ることができた。細孔径の異なる触媒を作製し、CPP法によりVGOとARの接触分解を検討した結果、VGOでは細孔径の影響が顕著であったが、ARでは細孔径の影響が極めて小さいことが分かった。, Zeolite containing mesoporous SiO2-Al2O3 catalysts with three layered-hierarchical structures were prepared using the gel skeletal reinforcement methods. Catalytic cracking of soybean oil was performed using Curie point pyrolyzer (CPP) which was demonstrated as a promising method for estimation of processing of heavy hydrocarbon resources. It was found that the multi/single branch ratios and conversion were improved with increasing hierarchical structure because the catalysts had the larger space. The gel skeletal reinforcement (GSR) method was developed to prepare silica-aluminas (GSR-SA) with different sizes of large mesopores. The effects of mesopore sizes of catalysts on catalytic cracking of vacuum gas oil (VGO) and atmospheric residue (AR) by CPP method were investigated using the mixed catalysts with zeolite and GSR-SA. It was found that the conversions of VGO increased with increasing pore size of catalysts while the effect of pore size on the conversion of AR was only slight., 2013年度～2015年度科学研究費補助金(基盤研究(B))研究成果報告書, 25289286},
 title = {階層構造を持つミクロ-メソ多孔性複合材料の創成とその触媒機能の解明},
 year = {2016},
 yomi = {イシハラ, アツシ and ナス, ヒロユキ and ハシモト, タダノリ}
}