{"created":"2023-06-19T11:43:40.241391+00:00","id":13301,"links":{},"metadata":{"_buckets":{"deposit":"d4e3e8aa-f935-4440-827b-f7d60f4abda4"},"_deposit":{"created_by":15,"id":"13301","owners":[15],"pid":{"revision_id":0,"type":"depid","value":"13301"},"status":"published"},"_oai":{"id":"oai:mie-u.repo.nii.ac.jp:00013301","sets":["366:680:1692685142618"]},"author_link":["43388","43389","43390"],"item_8_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2018-05-16","bibliographicIssueDateType":"Issued"}}]},"item_8_description_14":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_8_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"現在pH電極に用いられているLi伝導型のガラス電極には，汚れの蓄積により容易にpH応答が低下するという問題がある。この問題を解決するために二種類のメンテナンスフリーのpH電極を開発した。防汚特性に基づくセルフクリーニング機能を有する電子伝導ガラス電極の開発に関しては，既存のFe2O3-Bi2O3-B2O3ガラスより撥水性に優れたFe2O3-Bi2O3-GeO2ガラスの開発に成功した。一方，遷移金属酸化物をゾル-ゲルコーティングしたステンレス電極は，高いpH感度と高速pH応答を示した。加工性に優れる電極なのでディスポーザブルのpH電極として利用が期待される。","subitem_description_type":"Abstract"},{"subitem_description":"Commercially available pH electrodes have fatal problem that pH response is deteriorated by the accumulation of stain easily. In order to solve this problem, we developed two types of maintenance-free pH responsive electrodes which guarantees pH response performance by maintaining a clean state. Such pH electrodes cannot be realized with commercially available pH-responsive glass electrode. As for the development of a Li-free electronically conductive glass electrode having a self-cleaning function based on anti-fouling property (hydrophobicity), we developed Fe2O3-Bi2O3-GeO2 glasses with higher contact angle with water compared with the  previously reported Fe2O3-Bi2O3-B2O3 glasses. In addition, the stainless electrode sol-gel coated with transition metal oxide showed high pH sensitivity and fast pH response. This stainless electrodes with excellent processability are candidate for a disposable pH electrode.","subitem_description_type":"Abstract"}]},"item_8_description_5":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"2015年度～2017年度科学研究費補助金(基盤研究(C))研究成果報告書","subitem_description_type":"Other"}]},"item_8_description_64":{"attribute_name":"科研費番号","attribute_value_mlt":[{"subitem_description":"15K06439","subitem_description_type":"Other"}]},"item_8_publisher_30":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"三重大学"}]},"item_8_text_31":{"attribute_name":"出版者（ヨミ）","attribute_value_mlt":[{"subitem_text_value":"ミエダイガク"}]},"item_8_text_65":{"attribute_name":"資源タイプ（三重大）","attribute_value_mlt":[{"subitem_text_value":"Kaken / 科研費報告書"}]},"item_8_version_type_15":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"橋本, 忠範","creatorNameLang":"ja"},{"creatorName":"ハシモト, タダノリ","creatorNameLang":"ja-Kana"},{"creatorName":"HASHIMOTO, Tadanori","creatorNameLang":"en"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"石原, 篤","creatorNameLang":"ja"},{"creatorName":"イシハラ, アツシ","creatorNameLang":"ja-Kana"},{"creatorName":"ISHIHARA, Atsushi","creatorNameLang":"en"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"那須, 弘行","creatorNameLang":"ja"},{"creatorName":"ナス, ヒロユキ","creatorNameLang":"ja-Kana"},{"creatorName":"NASU, Hiroyuki","creatorNameLang":"en"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2020-01-22"}],"displaytype":"detail","filename":"2019RP0080.pdf","filesize":[{"value":"2.9 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"2019RP0080","url":"https://mie-u.repo.nii.ac.jp/record/13301/files/2019RP0080.pdf"},"version_id":"2fb2fbe4-b473-48ed-a823-8b5b3c2331c0"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"pH応答ガラス","subitem_subject_scheme":"Other"},{"subitem_subject":"セルフクリーニング機能","subitem_subject_scheme":"Other"},{"subitem_subject":"メンテナンスフリー","subitem_subject_scheme":"Other"},{"subitem_subject":"撥水性","subitem_subject_scheme":"Other"},{"subitem_subject":"電子伝導ガラス","subitem_subject_scheme":"Other"},{"subitem_subject":"ゾル-ゲルコーティング","subitem_subject_scheme":"Other"},{"subitem_subject":"ステンレス電極","subitem_subject_scheme":"Other"},{"subitem_subject":"ディスポーザブル電極","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"research report","resourceuri":"http://purl.org/coar/resource_type/c_18ws"}]},"item_title":"セルフクリーニングpH電極ならびにディスポーザブルpH電極の開発","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"セルフクリーニングpH電極ならびにディスポーザブルpH電極の開発","subitem_title_language":"ja"},{"subitem_title":"Development of self-cleaning pH electrodes and disposable pH electrodes","subitem_title_language":"en"}]},"item_type_id":"8","owner":"15","path":["1692685142618"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2020-01-22"},"publish_date":"2020-01-22","publish_status":"0","recid":"13301","relation_version_is_last":true,"title":["セルフクリーニングpH電極ならびにディスポーザブルpH電極の開発"],"weko_creator_id":"15","weko_shared_id":-1},"updated":"2023-11-20T00:47:43.232137+00:00"}