{"created":"2023-06-19T11:45:05.361150+00:00","id":15308,"links":{},"metadata":{"_buckets":{"deposit":"ef21d0a7-07c0-4479-941a-55ed328a63a7"},"_deposit":{"created_by":15,"id":"15308","owners":[15],"pid":{"revision_id":0,"type":"depid","value":"15308"},"status":"published"},"_oai":{"id":"oai:mie-u.repo.nii.ac.jp:00015308","sets":["366:680:1692685258258"]},"author_link":["50694","50695","50696"],"item_8_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2021-05-13","bibliographicIssueDateType":"Issued"}}]},"item_8_description_14":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_8_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"液漏れしない比較電極に関しては，xAg(100-x)Teガラスがこれまでのガラスと比較して，比較電極に適していることがわかった。さらに加熱した25Ag75Teガラスはより適していることがわかった。この原因は，正方晶のAgの析出と関係づけられた。\n琺瑯電極に関しては，25Ag75Te/ステンレス構造とすることで本研究の中で最も比較電極に適した電極を得ることに成功した。この原因は，比較的珍しい六方晶のAg（もしくはAg2Te）の析出と関係づけられた。","subitem_description_type":"Abstract"},{"subitem_description":"An Ag/AgCl reference electrode that is built into commercially available pH electrodes leaks its internal KCl solution via a liquid junction. This leakage is disadvantageous because the test solution is contaminated by a trace amount of the KCl solution. The applicability of Ag2O-TeO2 glasses to reference electrodes for pH sensors was investigated in this study. The effects of the Ag2O content and heat treatment on the pH sensitivity of these glasses and the pH sensitivity of the Ag2O-TeO2 glass/stainless steel electrodes were examined. The pH sensitivity of Ag2O-TeO2 glasses increased as the Ag2O content increased, but it was less than 40 % and was the lowest among the glasses that have been investigated to date. The 25Ag2O･75TeO2 glass/stainless steel electrodes precipitated cubic Ag and hexagonal Ag and showed relatively low pH sensitivities of 26 % and 5 %, respectively. Thus, the hexagonal Ag-precipitated samples were considered candidate reference electrodes for pH sensors.","subitem_description_type":"Abstract"}]},"item_8_description_5":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"2018年度～2020年度科学研究費補助金(基盤研究(C))研究成果報告書","subitem_description_type":"Other"}]},"item_8_description_64":{"attribute_name":"科研費番号","attribute_value_mlt":[{"subitem_description":"18K04702","subitem_description_type":"Other"}]},"item_8_publisher_30":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"三重大学"}]},"item_8_text_31":{"attribute_name":"出版者（ヨミ）","attribute_value_mlt":[{"subitem_text_value":"ミエダイガク"}]},"item_8_text_65":{"attribute_name":"資源タイプ（三重大）","attribute_value_mlt":[{"subitem_text_value":"Kaken / 科研費報告書"}]},"item_8_version_type_15":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"橋本, 忠範","creatorNameLang":"ja"},{"creatorName":"ハシモト, タダノリ","creatorNameLang":"ja-Kana"},{"creatorName":"Hashimoto, Tadanori","creatorNameLang":"en"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"石原, 篤","creatorNameLang":"ja"},{"creatorName":"イシハラ, アツシ","creatorNameLang":"ja-Kana"},{"creatorName":"Ishihara, Atsushi","creatorNameLang":"en"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"那須, 弘行","creatorNameLang":"ja"},{"creatorName":"ナス, ヒロユキ","creatorNameLang":"ja-Kana"},{"creatorName":"Nasu, Hiroyuki","creatorNameLang":"en"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2022-11-29"}],"displaytype":"detail","filename":"2022RP0069.pdf","filesize":[{"value":"654.5 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"2022RP0069","url":"https://mie-u.repo.nii.ac.jp/record/15308/files/2022RP0069.pdf"},"version_id":"e8c2bde7-33a1-401b-adc8-a3005a3444ab"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"pH応答電極","subitem_subject_scheme":"Other"},{"subitem_subject":"ガラス電極","subitem_subject_scheme":"Other"},{"subitem_subject":"金属電極","subitem_subject_scheme":"Other"},{"subitem_subject":"琺瑯電極","subitem_subject_scheme":"Other"},{"subitem_subject":"比較電極","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"research report","resourceuri":"http://purl.org/coar/resource_type/c_18ws"}]},"item_title":"液漏れしない比較電極および琺瑯電極の開発","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"液漏れしない比較電極および琺瑯電極の開発","subitem_title_language":"ja"},{"subitem_title":"Development of Referenc Electrodes without Internal Liquid Leakage and Enamel Electrodes","subitem_title_language":"en"}]},"item_type_id":"8","owner":"15","path":["1692685258258"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2022-11-29"},"publish_date":"2022-11-29","publish_status":"0","recid":"15308","relation_version_is_last":true,"title":["液漏れしない比較電極および琺瑯電極の開発"],"weko_creator_id":"15","weko_shared_id":-1},"updated":"2023-11-20T02:11:49.427382+00:00"}