{"created":"2023-12-19T04:25:54.626815+00:00","id":2000229,"links":{},"metadata":{"_buckets":{"deposit":"9e0a76f8-86ad-4139-9fe3-a03646bc5e42"},"_deposit":{"created_by":15,"id":"2000229","owner":"15","owners":[15],"pid":{"revision_id":0,"type":"depid","value":"2000229"},"status":"published"},"_oai":{"id":"oai:mie-u.repo.nii.ac.jp:02000229","sets":["366:680:1701929300332"]},"author_link":[],"control_number":"2000229","item_8_biblio_info_6":{"attribute_name":"bibliographic_information","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2022-05-24","bibliographicIssueDateType":"Issued"}}]},"item_8_description_14":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_8_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"リンをドープした芳香族環構造を有するg-C3N4は、簡便な焼成法で合成することに成功した。 実験結果は、組み込まれたドーパントが可視光吸収と電荷キャリアの分離を促進することを示した。 最適なドープ量の芳香環とリンを含むリンと芳香環をドープしたg-C3N4は、550μmol/ h / gの水素生成速度を示した。これは、元のg-C3N4（120μmol/ h / g）よりも著しく高い水素生成速度である。 本研究は、リンと芳香環をドープしたg-C3N4が、効果的な太陽エネルギー変換を備えた潜在的な光触媒であることを示している。","subitem_description_type":"Abstract"},{"subitem_description":"Phosphorus doped g-C3N4 with aromatic ring structure was successfully synthesized by a simple calcination method. Experimental results showed that the incorporated dopants promote the visible light absorption and the separation of charge carriers. Phosphorus and aromatic ring doped g-C3N4 with optimal loading amounts of aromatic and phosphorus showed the highest hydrogen production rate of 550 μmol/h/g, which is remarkably higher than that of pristine g-C3N4 (120 μmol/h/g). This work demonstrates that phosphorus and aromatic ring doped g-C3N4 are potential photocatalysts with effective solar energy conversion.","subitem_description_type":"Abstract"}]},"item_8_description_5":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"2018年度～2021年度科学研究費補助金(基盤研究(B))研究成果報告書","subitem_description_type":"Other"}]},"item_8_description_64":{"attribute_name":"科研費番号","attribute_value_mlt":[{"subitem_description":"18H02013","subitem_description_type":"Other"}]},"item_8_publisher_30":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"三重大学"}]},"item_8_text_31":{"attribute_name":"出版者（ヨミ）","attribute_value_mlt":[{"subitem_text_value":"ミエダイガク"}]},"item_8_text_65":{"attribute_name":"item_8_text_65","attribute_value_mlt":[{"subitem_text_value":"Kaken / 科研費報告書"}]},"item_8_version_type_15":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"勝又, 英之","creatorNameLang":"ja"},{"creatorName":"KATSUMATA, Hideyuki","creatorNameLang":"en"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_access","date":[{"dateType":"Available","dateValue":"2023-12-19"}],"filename":"2023RP0066.pdf","filesize":[{"value":"239 KB"}],"format":"application/pdf","mimetype":"application/pdf","url":{"url":"https://mie-u.repo.nii.ac.jp/record/2000229/files/2023RP0066.pdf"},"version_id":"c62ab47d-18df-447c-aa13-2087c6937042"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"グラファイト状窒化炭素","subitem_subject_scheme":"Other"},{"subitem_subject":"分子内修飾","subitem_subject_scheme":"Other"},{"subitem_subject":"非金属ドープ","subitem_subject_scheme":"Other"},{"subitem_subject":"可視光","subitem_subject_scheme":"Other"},{"subitem_subject":"水分解","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"item_resource_type","attribute_value_mlt":[{"resourcetype":"research report","resourceuri":"http://purl.org/coar/resource_type/c_18ws"}]},"item_title":"分子内モディフィケーション高分子材料に立脚した太陽光広域利用型光触媒の高性能化","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"分子内モディフィケーション高分子材料に立脚した太陽光広域利用型光触媒の高性能化","subitem_title_language":"ja"},{"subitem_title":"Enhanced photocatalytic activity of wide solar spectra usage type photocatalyst based on intramolecular modified polymer material","subitem_title_language":"en"}]},"item_type_id":"8","owner":"15","path":["1701929300332"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2023-12-19"},"publish_date":"2023-12-19","publish_status":"0","recid":"2000229","relation_version_is_last":true,"title":["分子内モディフィケーション高分子材料に立脚した太陽光広域利用型光触媒の高性能化"],"weko_creator_id":"15","weko_shared_id":-1},"updated":"2024-09-24T04:43:41.486362+00:00"}