{"created":"2023-12-22T05:16:45.748066+00:00","id":2000281,"links":{},"metadata":{"_buckets":{"deposit":"d8843d17-634f-4021-888a-dbf3d3b1f583"},"_deposit":{"created_by":15,"id":"2000281","owner":"15","owners":[15],"pid":{"revision_id":0,"type":"depid","value":"2000281"},"status":"published"},"_oai":{"id":"oai:mie-u.repo.nii.ac.jp:02000281","sets":["515:756:1701929619706"]},"author_link":[],"control_number":"2000281","item_8_biblio_info_6":{"attribute_name":"bibliographic_information","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2022-05-17","bibliographicIssueDateType":"Issued"}}]},"item_8_description_14":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_8_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"イオン液体は、グリーンケミストリーの環境にやさしい溶媒として注目されている。本研究では、イオン液体中でアルドール縮合環化によるトルキセン型多環式化合物の合成に挑戦した。\nイオン液体[BMIM][Tf2N]または[BMIM][BF4]中で、p-TsOH存在下、1-インダノンのアルドール縮合二量体と置換アセナフテノンを加熱したところ、ベンゾトルキセン誘導体とアルドール環化三量体が生成した。また、二量体と、2-アセチルフルオレンまたは5-アセチルアセナフテンにより、アルドール縮合環化した。生成物も抽出のみで分離でき、省力化が達成できた。今後、多くの機能性分子の環境にやさしい合成への発展が期待される。","subitem_description_type":"Abstract"},{"subitem_description":"Ionic liquids have attracted a great deal of interest as environmentally green solvents in recent years. We studied the synthesis of novel benzotruxenes in ionic liquids by acid-catalyzed aldol cyclocondensation. Mixtures of 2-(1-indanylidene) indan-1-one and substituted 1-acenaphthenones were heated at 100 oC in ionic liquid [BMIM][Tf2N] or [BMIM][BF4] in the presence of p-TsOH. The products were extracted with toluene and purified by SiO2 column chromatography and recrystallization to give pure novel benzotruxenes. The aldol cyclocondesation of acetylarenes and 2-(1-indanylidene) indan-1-one gave novel polycyclic aromatic compounds. In summary, ionic liquid could be applied in environmentally green synthesis of novel polycyclic aromatic compounds.","subitem_description_type":"Abstract"}]},"item_8_description_5":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"2019年度～2021年度科学研究費補助金(基盤研究(C))研究成果報告書","subitem_description_type":"Other"}]},"item_8_description_64":{"attribute_name":"科研費番号","attribute_value_mlt":[{"subitem_description":"19K05564","subitem_description_type":"Other"}]},"item_8_publisher_30":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"三重大学"}]},"item_8_text_31":{"attribute_name":"出版者（ヨミ）","attribute_value_mlt":[{"subitem_text_value":"ミエダイガク"}]},"item_8_text_65":{"attribute_name":"item_8_text_65","attribute_value_mlt":[{"subitem_text_value":"Kaken / 科研費報告書"}]},"item_8_version_type_15":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"岡崎, 隆男","creatorNameLang":"ja"},{"creatorName":"Okazaki, Takao","creatorNameLang":"en"}]},{"creatorNames":[{"creatorName":"北川, 敏一","creatorNameLang":"ja"},{"creatorName":"Kitagawa, Toshikazu","creatorNameLang":"en"}]},{"creatorNames":[{"creatorName":"平井, 克幸","creatorNameLang":"ja"},{"creatorName":"Hirai, Katsuyuki","creatorNameLang":"en"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_access","date":[{"dateType":"Available","dateValue":"2023-12-22"}],"filename":"2023RP0101.pdf","filesize":[{"value":"842 KB"}],"format":"application/pdf","mimetype":"application/pdf","url":{"url":"https://mie-u.repo.nii.ac.jp/record/2000281/files/2023RP0101.pdf"},"version_id":"8c9b9c3c-2267-41a6-b34b-410a3db2c59a"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"イオン液体","subitem_subject_scheme":"Other"},{"subitem_subject":"トルキセン","subitem_subject_scheme":"Other"},{"subitem_subject":"アルドール環化三量化","subitem_subject_scheme":"Other"},{"subitem_subject":"アルドール縮合環化","subitem_subject_scheme":"Other"},{"subitem_subject":"多環芳香族炭化水素","subitem_subject_scheme":"Other"},{"subitem_subject":"グリー ンケミストリー","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"item_resource_type","attribute_value_mlt":[{"resourcetype":"research report","resourceuri":"http://purl.org/coar/resource_type/c_18ws"}]},"item_title":"環境にやさしいイオン液体と省力化：反応機構解析に基づくトルキセン型分子の合成","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"環境にやさしいイオン液体と省力化：反応機構解析に基づくトルキセン型分子の合成","subitem_title_language":"ja"},{"subitem_title":"Environmentally Friendly Ionic Liquids and Labor-saving: Synthesis of Truxene-type Molecules on the Basis of Analysis of Reaction Mechanisms","subitem_title_language":"en"}]},"item_type_id":"8","owner":"15","path":["1701929619706"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2023-12-22"},"publish_date":"2023-12-22","publish_status":"0","recid":"2000281","relation_version_is_last":true,"title":["環境にやさしいイオン液体と省力化：反応機構解析に基づくトルキセン型分子の合成"],"weko_creator_id":"15","weko_shared_id":-1},"updated":"2024-09-25T04:11:28.451255+00:00"}