{"created":"2024-10-25T00:11:12.267587+00:00","id":2000998,"links":{},"metadata":{"_buckets":{"deposit":"ece2612e-e004-430a-a94d-3d2a997e9576"},"_deposit":{"created_by":15,"id":"2000998","owner":"15","owners":[15],"pid":{"revision_id":0,"type":"depid","value":"2000998"},"status":"published"},"_oai":{"id":"oai:mie-u.repo.nii.ac.jp:02000998","sets":["366:680:1728958155548"]},"author_link":[],"item_8_biblio_info_6":{"attribute_name":"bibliographic_information","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2023-05-19","bibliographicIssueDateType":"Issued"}}]},"item_8_description_14":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_8_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"三重項カルベンは中性２配位の炭素原子に２個の不対電子をもつ有機分子種であり、安定化が非常に困難な活性種である。従来我々は、これをπ共役と立体保護により安定化できることを示したが、主に二量化により減衰してしまうため、完全に安定な状態に保つには至っていない。本研究では、三重項カルベンの長寿命化の新たな方法を探索するため、これをAu基板表面の自己組織化単分子膜に固定した状態で発生させ、捕捉剤とカルベンの結合効率を調べることにより、膜上で分子運動を束縛された状態では二量化を効果的に抑制できることを明らかにした。","subitem_description_language":"ja","subitem_description_type":"Abstract"},{"subitem_description":"Triplet carbenes are highly reactive organic species containing a divalent neutral carbon atom. Although we previously found that they can be stabilized by pi-conjugation and steric protection, it is still difficult to prepare them in a completely stable form because of rapid deterioration by dimerization. In the present study, further stabilization of triplet carbene was examined by generating it in a self-assembled monolayer, in which each carbene molecule was fixed on the solid surface. It was shown that carbenes under such conditions can be effectively prohibited from dimerization.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_8_description_5":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"2020年度～2022年度科学研究費補助金(基盤研究(C))研究成果報告書","subitem_description_type":"Other"}]},"item_8_description_64":{"attribute_name":"科研費番号","attribute_value_mlt":[{"subitem_description":"20K05462","subitem_description_type":"Other"}]},"item_8_publisher_30":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"三重大学"}]},"item_8_text_31":{"attribute_name":"出版者（ヨミ）","attribute_value_mlt":[{"subitem_text_value":"ミエダイガク"}]},"item_8_text_65":{"attribute_name":"item_8_text_65","attribute_value_mlt":[{"subitem_text_value":"Kaken / 科研費報告書"}]},"item_8_version_type_15":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"北川, 敏一","creatorNameLang":"ja"},{"creatorName":"Kitagawa, Toshikazu","creatorNameLang":"en"}]},{"creatorNames":[{"creatorName":"平井, 克幸","creatorNameLang":"ja"},{"creatorName":"HIRAI, Katsuyuki","creatorNameLang":"en"}]},{"creatorNames":[{"creatorName":"岡崎, 隆男","creatorNameLang":"ja"},{"creatorName":"OKAZAKI, Takao","creatorNameLang":"en"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_access","date":[{"dateType":"Available","dateValue":"2024-10-25"}],"filename":"2024RP0088.pdf","filesize":[{"value":"151 KB"}],"format":"application/pdf","url":{"label":"2024RP0088.pdf","url":"https://mie-u.repo.nii.ac.jp/record/2000998/files/2024RP0088.pdf"},"version_id":"bed06c81-3775-4e79-b20f-8289257a3ee4"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"三重項カルベン","subitem_subject_scheme":"Other"},{"subitem_subject":"ジアゾメタン","subitem_subject_scheme":"Other"},{"subitem_subject":"分子三脚","subitem_subject_scheme":"Other"},{"subitem_subject":"アダマンタン","subitem_subject_scheme":"Other"},{"subitem_subject":"自己組織化単分子膜","subitem_subject_scheme":"Other"},{"subitem_subject":"光化学反応","subitem_subject_scheme":"Other"},{"subitem_subject":"サイクリックボルタンメトリー","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"item_resource_type","attribute_value_mlt":[{"resourcetype":"research report","resourceuri":"http://purl.org/coar/resource_type/c_18ws"}]},"item_title":"分子三脚単分子膜上への拘束による三重項カルベンの完全安定化","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"分子三脚単分子膜上への拘束による三重項カルベンの完全安定化","subitem_title_language":"ja"},{"subitem_title":"Complete stabilization of triplet carbenes by immobilization through self-assembled monolayer of tripod-shaped trithiol","subitem_title_language":"en"}]},"item_type_id":"8","owner":"15","path":["1728958155548"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2024-10-25"},"publish_date":"2024-10-25","publish_status":"0","recid":"2000998","relation_version_is_last":true,"title":["分子三脚単分子膜上への拘束による三重項カルベンの完全安定化"],"weko_creator_id":"15","weko_shared_id":-1},"updated":"2024-10-25T00:26:28.762351+00:00"}