{"created":"2023-06-19T11:36:03.589984+00:00","id":2886,"links":{},"metadata":{"_buckets":{"deposit":"2d391821-96bb-443c-a57b-cc0ceed03f12"},"_deposit":{"created_by":13,"id":"2886","owners":[13],"pid":{"revision_id":0,"type":"depid","value":"2886"},"status":"published"},"_oai":{"id":"oai:mie-u.repo.nii.ac.jp:00002886","sets":["143:144:234:240"]},"author_link":["37353","37354","37355"],"item_4_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"1983-03-01","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"65","bibliographicPageStart":"59","bibliographicVolumeNumber":"34","bibliographic_titles":[{"bibliographic_title":"三重大学教育学部研究紀要. 自然科学"}]}]},"item_4_description_14":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_4_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Bis(2,2'-bipyridine)ruthenium(Ⅱ) complexes of the<special> [<special>Ru(bpy)2</special>(L-L)]n+</special> type, where L-L is S-S or O-O bidentate ligand, were synthesized and their electrochemical and photochemical properties were examined. All the complexes undergo one-electron oxidation, and two one-electron reductions. They are all reversible or quasi-reversible. The redox potentials of Ru(Ⅱ)/Ru(Ⅲ), <special>EOX1/2</special>, increase as the energies of the metal to ligand charge transfer(MLCT) transition increase. The <special>EOX1/2</special> values indicate that the σ-donor ability of L-L ligands decreases in the order of dtc>acac><special>S2PPh2</special>~dbm>bzac><special>S2P(OEt)2</special>>bztfac>hfac><special>bpy+)</special>. The complexes containing O-O ligands exhibit emissinons in visible region, the origin of which are probably from a MLCT excited state.","subitem_description_type":"Abstract"}]},"item_4_publisher_30":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"三重大学教育学部"}]},"item_4_source_id_7":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0389-9225","subitem_source_identifier_type":"PISSN"}]},"item_4_source_id_9":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AN00234199","subitem_source_identifier_type":"NCID"}]},"item_4_text_18":{"attribute_name":"その他のタイトル","attribute_value_mlt":[{"subitem_text_language":"en","subitem_text_value":"Electrochemical and Photochemical Properties of Bis (2, 2'-bipyridine) Ruthenium (II) Complexes Containing S-S and O-O Bidentate Ligands"}]},"item_4_text_65":{"attribute_name":"資源タイプ（三重大）","attribute_value_mlt":[{"subitem_text_value":"Departmental Bulletin Paper / 紀要論文"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"metadata only access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_14cb"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"芳賀, 正明","creatorNameLang":"ja"},{"creatorName":"Haga, Masa-aki","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"37353","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"金井, 洋","creatorNameLang":"ja"},{"creatorName":"Kanai, Hiroshi","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"37354","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"田中, 敏夫","creatorNameLang":"ja"},{"creatorName":"Tanaka, Toshio","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"37355","nameIdentifierScheme":"WEKO"}]}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"S-SおよびO-O二座配位子を含むビス(2, 2'-ビピリジン)ルテニウム(II)錯体の電気化学的及び光化学的性質","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"S-SおよびO-O二座配位子を含むビス(2, 2'-ビピリジン)ルテニウム(II)錯体の電気化学的及び光化学的性質","subitem_title_language":"ja"}]},"item_type_id":"4","owner":"13","path":["240"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2018-03-16"},"publish_date":"2018-03-16","publish_status":"0","recid":"2886","relation_version_is_last":true,"title":["S-SおよびO-O二座配位子を含むビス(2, 2'-ビピリジン)ルテニウム(II)錯体の電気化学的及び光化学的性質"],"weko_creator_id":"13","weko_shared_id":-1},"updated":"2023-11-07T01:39:38.884571+00:00"}