{"created":"2023-06-19T11:37:36.109147+00:00","id":4971,"links":{},"metadata":{"_buckets":{"deposit":"11617708-e945-47e3-9f7a-e29bde78f6d9"},"_deposit":{"created_by":13,"id":"4971","owners":[13],"pid":{"revision_id":0,"type":"depid","value":"4971"},"status":"published"},"_oai":{"id":"oai:mie-u.repo.nii.ac.jp:00004971","sets":["366:367:368:387"]},"author_link":["10619","10620","10621"],"item_4_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"1994-12-21","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"80","bibliographicPageStart":"73","bibliographicVolumeNumber":"19","bibliographic_titles":[{"bibliographic_title":"Research reports of the Faculty of Engineering, Mie University"}]}]},"item_4_description_14":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_4_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"The Wittig reactions between benzo[c]thiophene-1,3-dicarbaldehyde(2)and 2,5-dialkyloxy-p-xylylenebis (triphenylphosphonium bromide)s(7)were carried out to obtain poly (1,3-benzo[c]thiophenediylvinylene-alt-2,5-dialkyloxy-1,4-phenylenevinylene)s (8), where aklyloxy is hexyloxy (8a), octyloxy (8b), or dodecyloxy (8c). The longer the alkyloxy group, the higher the degree of polymerization of the product. The optical band gap of poly (1,3-benzo[c]thiophenediylvinylene-alt-2,5-didodecyloxy-1,4-phenylenevinylene) (8c)was found to be 1.7 eV. This value was much lower than that of poly (1,4-phenylenevinylene-alt-2,5-didodecyloxy-1,4-phenylenevinylene) (2.5 eV).","subitem_description_type":"Abstract"}]},"item_4_publisher_30":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Faculty of Engineering, Mie University"}]},"item_4_source_id_7":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0385-6208","subitem_source_identifier_type":"PISSN"}]},"item_4_source_id_9":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA00816341","subitem_source_identifier_type":"NCID"}]},"item_4_text_18":{"attribute_name":"その他のタイトル","attribute_value_mlt":[{"subitem_text_language":"ja","subitem_text_value":"ベンゾ[C]チオフェンを有するポリ(アリレンビニレン)の合成"}]},"item_4_text_65":{"attribute_name":"資源タイプ（三重大）","attribute_value_mlt":[{"subitem_text_value":"Departmental Bulletin Paper / 紀要論文"}]},"item_4_version_type_15":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Kubo, Masataka","creatorNameLang":"en"},{"creatorName":"久保, 雅敬","creatorNameLang":"ja"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Itoh, Takahito","creatorNameLang":"en"},{"creatorName":"伊藤, 敬人","creatorNameLang":"ja"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Iwatsuki, Shouji","creatorNameLang":"en"},{"creatorName":"岩月, 章治","creatorNameLang":"ja"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2017-02-18"}],"displaytype":"detail","filename":"AA008163410190009.PDF","filesize":[{"value":"477.8 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"AA008163410190009.PDF","url":"https://mie-u.repo.nii.ac.jp/record/4971/files/AA008163410190009.PDF"},"version_id":"e2edb790-5768-4537-ae17-2f9c966f6047"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"Poly(arylenevinylene)","subitem_subject_scheme":"Other"},{"subitem_subject":"Benzo[c]thiophene","subitem_subject_scheme":"Other"},{"subitem_subject":"wittig reaction","subitem_subject_scheme":"Other"},{"subitem_subject":"optical bandgap","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Synthesis of Poly(arylenevinylene)s Carrying Benzo[C]-thiophene as Arylene Unit","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Synthesis of Poly(arylenevinylene)s Carrying Benzo[C]-thiophene as Arylene Unit","subitem_title_language":"en"}]},"item_type_id":"4","owner":"13","path":["387"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2007-07-02"},"publish_date":"2007-07-02","publish_status":"0","recid":"4971","relation_version_is_last":true,"title":["Synthesis of Poly(arylenevinylene)s Carrying Benzo[C]-thiophene as Arylene Unit"],"weko_creator_id":"13","weko_shared_id":-1},"updated":"2023-10-05T06:25:10.502589+00:00"}