{"created":"2023-06-19T11:38:33.956980+00:00","id":6277,"links":{},"metadata":{"_buckets":{"deposit":"528b07f7-68ea-418f-a6a4-8f91ca67e8b7"},"_deposit":{"created_by":13,"id":"6277","owners":[13],"pid":{"revision_id":0,"type":"depid","value":"6277"},"status":"published"},"_oai":{"id":"oai:mie-u.repo.nii.ac.jp:00006277","sets":["420:421:491:496"]},"author_link":["14209","14210"],"item_4_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"1987-02-01","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"109","bibliographicPageStart":"97","bibliographicVolumeNumber":"15","bibliographic_titles":[{"bibliographic_title":"三重大學農學部演習林報告 = Bulletin of the Mie University Forests"}]}]},"item_4_description_14":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_4_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"A novel procedure has been developed for selective cleavage of Cα-aryl bonds in lignin. This method was termed \"Phenyl Nucleus-Exchange Method\" (NE-method), based on the style of reaction. The impotant characteristic of NE-method is to dealkylate diphenylmethane type structural units involving lignin phenyl nuclei following the formation of such structures by lignin in a high yield by NE-method. In the present paper,the theory of NE-method and the degradation mechanism of lignin are outlined, and the application of NE-method for natural polyphenols and related substances is described.","subitem_description_type":"Abstract"},{"subitem_description":"リグニンの側鎖-芳香核間結合を選択的に開裂させる新たな手法（核交換法，NE-法）を開\n発した。NE-法は酸および大過剰のフェノール類のの存在下において，ジフェニルメタン型構造\n単位を選択的にに脱アルキル化するものであり，また同時にメトキシル基も脱メチル化され，リグ\nニンから最終生成物として多価フェノールが高収率で遊離する。NE-法はリグニンに限定され\nず，天然ポリフェノールおよび関連物質の構造研究および利用分野に広く利用することが可能で\nある。","subitem_description_type":"Abstract"}]},"item_4_publisher_30":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"三重大学農学部附属演習林"}]},"item_4_source_id_7":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0544-1005","subitem_source_identifier_type":"PISSN"}]},"item_4_source_id_9":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AN00234315","subitem_source_identifier_type":"NCID"}]},"item_4_subject_16":{"attribute_name":"日本十進分類法","attribute_value_mlt":[{"subitem_subject":"650","subitem_subject_scheme":"NDC"}]},"item_4_text_18":{"attribute_name":"その他のタイトル","attribute_value_mlt":[{"subitem_text_language":"ja","subitem_text_value":"リグニン側鎖-芳香核間結合の選択的開裂"}]},"item_4_text_63":{"attribute_name":"ノート","attribute_value_mlt":[{"subitem_text_value":"Agropedia提供データ"}]},"item_4_text_65":{"attribute_name":"資源タイプ（三重大）","attribute_value_mlt":[{"subitem_text_value":"Departmental Bulletin Paper / 紀要論文"}]},"item_4_version_type_15":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Funaoka, Masamitsu","creatorNameLang":"en"},{"creatorName":"船岡, 正光","creatorNameLang":"ja"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Abe, Isao","creatorNameLang":"en"},{"creatorName":"阿部, 勲","creatorNameLang":"ja"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2017-02-18"}],"displaytype":"detail","filename":"AN002343150001502.pdf","filesize":[{"value":"509.5 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"AN002343150001502.pdf","url":"https://mie-u.repo.nii.ac.jp/record/6277/files/AN002343150001502.pdf"},"version_id":"1aeeb490-678d-4bd6-a262-e56ae4782e05"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Selective Cleavage of Cα-Aryl Bonds in Lignin","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Selective Cleavage of Cα-Aryl Bonds in Lignin","subitem_title_language":"en"}]},"item_type_id":"4","owner":"13","path":["496"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2007-06-11"},"publish_date":"2007-06-11","publish_status":"0","recid":"6277","relation_version_is_last":true,"title":["Selective Cleavage of Cα-Aryl Bonds in Lignin"],"weko_creator_id":"13","weko_shared_id":-1},"updated":"2023-10-16T07:40:57.740221+00:00"}