{"created":"2023-06-19T11:39:57.600302+00:00","id":8206,"links":{},"metadata":{"_buckets":{"deposit":"7b5114db-d7c4-41df-ae4c-054df1de0b7c"},"_deposit":{"created_by":15,"id":"8206","owners":[15],"pid":{"revision_id":0,"type":"depid","value":"8206"},"status":"published"},"_oai":{"id":"oai:mie-u.repo.nii.ac.jp:00008206","sets":["366:638:639"]},"author_link":["20611","20612","20613","20614","20615"],"item_10001_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"1996-11-01","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"1215","bibliographicPageEnd":"1014","bibliographicPageStart":"1008","bibliographicVolumeNumber":"104","bibliographic_titles":[{"bibliographic_title":"日本セラミックス協会学術論文誌"}]}]},"item_10001_description_19":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_10001_description_5":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"The third order nonlinear optical susceptibilities X^<(3)> of Sb_2O_3-B_2O_3 binary glasses have been measured by the third harmonic generation (THG) method. The IR and Raman spectroscopic study reconfirmed that the structure of Sb_2O_3 glass is similar not to senarmontite but to valentinite which consists of double-chains of SbO_3 units. The formation of BO_4 units is much smaller for Sb_2O_3-B_2O_3 glasses than Bi_2O_3-B_2O_3 glasses at all compositions, which is ascribed to the covalent character of Sb-O bonds. It is also considered that Sb_2O_3 is present as SbO_3 trigonal units and participates in the glass network formation through the Sb-O-B bonds. The X^<(3)> value increased monotonically with increasing Sb_2O_3 content up to 8.4 × 10^<-13> esu for Sb_2O_3 glass, which is about 30 times larger than SiO_2 glass. Modified Lines'linear relationship between X^<(3)> and (n_ω^2+2)^3・(n_ω^2-1)・E_d/E_0^2 was adopted to Sb_2O_3-B_2O_3 glasses.","subitem_description_type":"Abstract"}]},"item_10001_publisher_8":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"日本セラミックス協会"}]},"item_10001_relation_42":{"attribute_name":"関係URI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"http://ci.nii.ac.jp/naid/110002291391/"}]}]},"item_10001_rights_15":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"社団法人日本セラミックス協会"},{"subitem_rights":"本文データは学協会の許諾に基づきCiNiiから複製したものである"}]},"item_10001_source_id_11":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AN10040326","subitem_source_identifier_type":"NCID"}]},"item_10001_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0914-5400","subitem_source_identifier_type":"PISSN"}]},"item_10001_subject_21":{"attribute_name":"日本十進分類法","attribute_value_mlt":[{"subitem_subject":"570","subitem_subject_scheme":"NDC"}]},"item_10001_text_25":{"attribute_name":"その他のタイトル","attribute_value_mlt":[{"subitem_text_value":"Sb_2O_3-B_2O_3 二成分系ガラスの構造と非線形光学特性"}]},"item_10001_text_70":{"attribute_name":"資源タイプ（三重大）","attribute_value_mlt":[{"subitem_text_value":"Journal Article / 学術雑誌論文"}]},"item_10001_version_type_20":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"TERASHIMA, Kentaro","creatorNameLang":"en"},{"creatorName":"寺島, 健太郎","creatorNameLang":"ja"}],"nameIdentifiers":[{"nameIdentifier":"20611","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"HASHIMOTO, Tadanori","creatorNameLang":"en"},{"creatorName":"橋本, 忠範","creatorNameLang":"ja"}],"nameIdentifiers":[{"nameIdentifier":"20612","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"UCHINO, Takashi","creatorNameLang":"en"},{"creatorName":"内野, 隆司","creatorNameLang":"ja"}],"nameIdentifiers":[{"nameIdentifier":"20613","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"KIM, Sae-Hoon","creatorNameLang":"en"},{"creatorName":"金, 世勲","creatorNameLang":"ja"}],"nameIdentifiers":[{"nameIdentifier":"20614","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"YOKO, Toshinobu","creatorNameLang":"en"},{"creatorName":"横尾, 俊信","creatorNameLang":"ja"}],"nameIdentifiers":[{"nameIdentifier":"20615","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2017-02-18"}],"displaytype":"detail","filename":"40A6651.pdf","filesize":[{"value":"963.9 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"40A6651.pdf","url":"https://mie-u.repo.nii.ac.jp/record/8206/files/40A6651.pdf"},"version_id":"aeb88ca3-ba34-4d57-b04d-68826ea1dcb6"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"Third harmonic generation","subitem_subject_scheme":"Other"},{"subitem_subject":"Senarmontite","subitem_subject_scheme":"Other"},{"subitem_subject":"Valentinite","subitem_subject_scheme":"Other"},{"subitem_subject":"Sb_2O_3 glass","subitem_subject_scheme":"Other"},{"subitem_subject":"Covalency","subitem_subject_scheme":"Other"},{"subitem_subject":"Modified Lines' relationship","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Structure and Nonlinear Optical Properties of Sb_2O_3-B_2O_3 Binary Glasses","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Structure and Nonlinear Optical Properties of Sb_2O_3-B_2O_3 Binary Glasses","subitem_title_language":"en"}]},"item_type_id":"10001","owner":"15","path":["639"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2008-03-06"},"publish_date":"2008-03-06","publish_status":"0","recid":"8206","relation_version_is_last":true,"title":["Structure and Nonlinear Optical Properties of Sb_2O_3-B_2O_3 Binary Glasses"],"weko_creator_id":"15","weko_shared_id":-1},"updated":"2023-10-13T02:10:47.833516+00:00"}