{"created":"2023-06-19T11:40:02.779552+00:00","id":8328,"links":{},"metadata":{"_buckets":{"deposit":"a01a7763-711f-4c8f-91ae-147042df0874"},"_deposit":{"created_by":15,"id":"8328","owners":[15],"pid":{"revision_id":0,"type":"depid","value":"8328"},"status":"published"},"_oai":{"id":"oai:mie-u.repo.nii.ac.jp:00008328","sets":["366:638:639"]},"author_link":[],"item_10001_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"1976-10-01","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"974","bibliographicPageEnd":"508","bibliographicPageStart":"496","bibliographicVolumeNumber":"84","bibliographic_titles":[{"bibliographic_title":"窯業協會誌 = Journal of the Ceramic Association, Japan"}]}]},"item_10001_description_19":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_10001_description_5":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"The electrical conductivities of glasses in the Ag2O-B2O3, Na2O-B2O3 and Ag2O-Na2O-B2O3 (Ag2O + Na2O = 27.4 mol% in average) systems have been determined over the temperature range from room temperature to about 400℃ using both d.c. and a.c. measurements. The temperature dependence of the electrical conductivities of the glasses could be described by the Rasch-Hinrichsen equation : σ = σ0exp (-ΔH/RT) The Ag2O-B2O3 glasses showed higher conductivity and lower activation energy for conduction than the Na2O-B2O3 glasses did. The mixed cation effect was observed in the Ag2O-Na2O-B2O3 system ; a minimum in the electrical conductivity and a maximum in the activation energy were found around the Ag/(Ag + Na) ratio of 1/5 on the property-composition curves. A minimum in the dielectric constant was also found. The magnitude of the mixed cation effect in the silver-containing system was, however, considerably smaller than that found in mixed-alkali glasses involving Li, Na, K or Cs ions. The electrical conductivity was much greater and the activation energy was smaller for the Ag2O-Na2O-B2O3 glasses of the composition range of Ag/(Ag + Na)>1/5, in which Ag+ ions are dominant current carries, than for the single cation Ag2O-B2O3 glasses of the same Ag2O content. This indicates that the mobility of Ag+ ions is increased on addition of Na+ ions in contrast with that of the alkali ions in mixed-alkali glasses which remains the same or is decreased on addition of alkali ions of the other type. Such behavior of the mobility of Ag+ ions was discussed by assuming the formation of Ag+ ion clusters which results in the shortening of the jump distances required for the migration of Ag+ ions.","subitem_description_type":"Abstract"}]},"item_10001_publisher_8":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"窯業協会"}]},"item_10001_relation_42":{"attribute_name":"関係URI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"http://ci.nii.ac.jp/naid/110002315848"}]}]},"item_10001_rights_15":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"社団法人日本セラミックス協会"},{"subitem_rights":"本文データは学協会の許諾に基づきCiNiiから複製したものである"}]},"item_10001_source_id_11":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AN00245650","subitem_source_identifier_type":"NCID"}]},"item_10001_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0009-0255","subitem_source_identifier_type":"PISSN"}]},"item_10001_text_25":{"attribute_name":"その他のタイトル","attribute_value_mlt":[{"subitem_text_value":"The electric conduction in mixed cation glasses of the Ag2O-Na2O-B2O3 system"}]},"item_10001_text_70":{"attribute_name":"資源タイプ（三重大）","attribute_value_mlt":[{"subitem_text_value":"Journal Article / 学術雑誌論文"}]},"item_10001_version_type_20":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"松下, 和正","creatorNameLang":"ja"},{"creatorName":"Matusita, Kazumasa","creatorNameLang":"en"}]},{"creatorNames":[{"creatorName":"伊藤, 増夫","creatorNameLang":"ja"},{"creatorName":"Ito, Masuo","creatorNameLang":"en"}]},{"creatorNames":[{"creatorName":"神谷, 寛一","creatorNameLang":"ja"},{"creatorName":"Kamiya, Kanichi","creatorNameLang":"en"}]},{"creatorNames":[{"creatorName":"作花, 済夫","creatorNameLang":"ja"},{"creatorName":"Sakka, Sumio","creatorNameLang":"en"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2017-02-18"}],"displaytype":"detail","filename":"40A11430.pdf","filesize":[{"value":"1.2 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"40A11430.pdf","url":"https://mie-u.repo.nii.ac.jp/record/8328/files/40A11430.pdf"},"version_id":"c80e05ae-d57a-4bb5-9699-ed748f98fa74"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Ag2O-Na2O-B2O3系混合カオチンガラスの電気泳動","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Ag2O-Na2O-B2O3系混合カオチンガラスの電気泳動","subitem_title_language":"ja"}]},"item_type_id":"10001","owner":"15","path":["639"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2010-03-02"},"publish_date":"2010-03-02","publish_status":"0","recid":"8328","relation_version_is_last":true,"title":["Ag2O-Na2O-B2O3系混合カオチンガラスの電気泳動"],"weko_creator_id":"15","weko_shared_id":-1},"updated":"2023-10-13T06:25:33.435056+00:00"}