{"_buckets": {"deposit": "9746aab0-b4dd-463e-8140-0407b37c1ec0"}, "_deposit": {"created_by": 15, "id": "10119", "owners": [15], "pid": {"revision_id": 0, "type": "depid", "value": "10119"}, "status": "published"}, "_oai": {"id": "oai:mie-u.repo.nii.ac.jp:00010119", "sets": ["1692685139729"]}, "author_link": ["25164", "25165", "25166", "25161", "25162", "25163"], "item_8_biblio_info_6": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2015-05-18", "bibliographicIssueDateType": "Issued"}}]}, "item_8_creator_3": {"attribute_name": "著者別名", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "HASHIMOTO, Tadanori", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "25164", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "ISHIHARA, Atsushi", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "25165", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "NASU, Hiroyuki", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "25166", "nameIdentifierScheme": "WEKO"}]}]}, "item_8_description_14": {"attribute_name": "フォーマット", "attribute_value_mlt": [{"subitem_description": "application/pdf", "subitem_description_type": "Other"}]}, "item_8_description_4": {"attribute_name": "抄録", "attribute_value_mlt": [{"subitem_description": "現在pH電極に用いられているLi伝導型のガラス電極には、汚れの蓄積により容易にpH応答が低下するという致命的な問題がある。この問題を解決するために、本研究では2つのタイプのメンテナンスフリーの電子伝導型pH応答ガラスを開発した。一つは、セルフクリーニング特性(光触媒活性と光誘起親水性)を有するTi3+を含有するTi02-P205（TP）ガラスである。もう一つは、防汚特性（撥水性）を有するFe203-Bi203-B203(FeBiB)ガラスである。これらのガラスは、レアメタルであるLiを使用せずに従来通りの高いpH感度を実現しつつ、従来とは異なる電子伝導を利用することで高速pH応答を実現した。", "subitem_description_type": "Abstract"}, {"subitem_description": "Commercially available pH electrodes (Li20-Si02-based glasses) have fatal problem that pH response is deteriorated by the accumulation of stain easily. In order to solve this problem, we developed two types of maintenance-free pH responsive glasses. The first one is Ti3+-containing Ti02-P205 (TP) glasses with self-cleaning property (photocatalytic activity and photo-induced hydrophilicity). The second one is Fe203-Bi203-B203 (FeBiB) glasses with anti-fouling property (hydrophobicity). In addition, we found that TP and FeBiB glasses show the quick pH response based on the electronic conduction as well as the high pH sensitivity.", "subitem_description_type": "Abstract"}]}, "item_8_description_5": {"attribute_name": "内容記述", "attribute_value_mlt": [{"subitem_description": "2012年度～2014年度科学研究費補助金(基盤研究(C))研究成果報告書", "subitem_description_type": "Other"}]}, "item_8_description_64": {"attribute_name": "科研費番号", "attribute_value_mlt": [{"subitem_description": "24560823", "subitem_description_type": "Other"}]}, "item_8_publisher_30": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "三重大学"}]}, "item_8_text_18": {"attribute_name": "その他のタイトル", "attribute_value_mlt": [{"subitem_text_value": "Development of Li-free self-cleaning glasses with quick pH response"}]}, "item_8_text_65": {"attribute_name": "資源タイプ（三重大）", "attribute_value_mlt": [{"subitem_text_value": "Kaken / 科研費報告書"}]}, "item_8_version_type_15": {"attribute_name": "著者版フラグ", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_970fb48d4fbd8a85", "subitem_version_type": "VoR"}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "橋本, 忠範", "creatorNameLang": "ja"}], "nameIdentifiers": [{"nameIdentifier": "25161", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "石原, 篤", "creatorNameLang": "ja"}], "nameIdentifiers": [{"nameIdentifier": "25162", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "那須, 弘行", "creatorNameLang": "ja"}], "nameIdentifiers": [{"nameIdentifier": "25163", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2017-02-20"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "40K17858.pdf", "filesize": [{"value": "592.6 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_note", "mimetype": "application/pdf", "size": 592600.0, "url": {"label": "40K17858.pdf", "url": "https://mie-u.repo.nii.ac.jp/record/10119/files/40K17858.pdf"}, "version_id": "9bbef193-94a5-4026-92ce-6080885e97c4"}]}, "item_keyword": {"attribute_name": "キーワード", "attribute_value_mlt": [{"subitem_subject": "pH応答ガラス", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Liフリー", "subitem_subject_scheme": "Other"}, {"subitem_subject": "電子伝導ガラス", "subitem_subject_scheme": "Other"}, {"subitem_subject": "メンテナンスフリー", "subitem_subject_scheme": "Other"}, {"subitem_subject": "光触媒活性", "subitem_subject_scheme": "Other"}, {"subitem_subject": "光誘起親水性", "subitem_subject_scheme": "Other"}, {"subitem_subject": "撥水性", "subitem_subject_scheme": "Other"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "jpn"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "research report", "resourceuri": "http://purl.org/coar/resource_type/c_18ws"}]}, "item_title": "Ｌｉを使用しない高速ｐＨ応答型のセルフクリーニングガラスの開発", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "Ｌｉを使用しない高速ｐＨ応答型のセルフクリーニングガラスの開発", "subitem_title_language": "ja"}]}, "item_type_id": "8", "owner": "15", "path": ["1692685139729"], "permalink_uri": "http://hdl.handle.net/10076/15445", "pubdate": {"attribute_name": "PubDate", "attribute_value": "2017-01-13"}, "publish_date": "2017-01-13", "publish_status": "0", "recid": "10119", "relation": {}, "relation_version_is_last": true, "title": ["Ｌｉを使用しない高速ｐＨ応答型のセルフクリーニングガラスの開発"], "weko_shared_id": -1}