{"_buckets": {"deposit": "d4e3e8aa-f935-4440-827b-f7d60f4abda4"}, "_deposit": {"created_by": 15, "id": "13301", "owners": [15], "pid": {"revision_id": 0, "type": "depid", "value": "13301"}, "status": "published"}, "_oai": {"id": "oai:mie-u.repo.nii.ac.jp:00013301", "sets": ["1692685142618"]}, "author_link": ["43394", "43395", "43396", "43391", "43392", "43393", "43388", "43389", "43390"], "item_8_biblio_info_6": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2018-05-16", "bibliographicIssueDateType": "Issued"}}]}, "item_8_creator_3": {"attribute_name": "著者別名", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "HASHIMOTO, Tadanori", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "43394", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "ISHIHARA, Atsushi", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "43395", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "NASU, Hiroyuki", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "43396", "nameIdentifierScheme": "WEKO"}]}]}, "item_8_description_14": {"attribute_name": "フォーマット", "attribute_value_mlt": [{"subitem_description": "application/pdf", "subitem_description_type": "Other"}]}, "item_8_description_4": {"attribute_name": "抄録", "attribute_value_mlt": [{"subitem_description": "現在pH電極に用いられているLi伝導型のガラス電極には，汚れの蓄積により容易にpH応答が低下するという問題がある。この問題を解決するために二種類のメンテナンスフリーのpH電極を開発した。防汚特性に基づくセルフクリーニング機能を有する電子伝導ガラス電極の開発に関しては，既存のFe2O3-Bi2O3-B2O3ガラスより撥水性に優れたFe2O3-Bi2O3-GeO2ガラスの開発に成功した。一方，遷移金属酸化物をゾル-ゲルコーティングしたステンレス電極は，高いpH感度と高速pH応答を示した。加工性に優れる電極なのでディスポーザブルのpH電極として利用が期待される。", "subitem_description_type": "Abstract"}, {"subitem_description": "Commercially available pH electrodes have fatal problem that pH response is deteriorated by the accumulation of stain easily. In order to solve this problem, we developed two types of maintenance-free pH responsive electrodes which guarantees pH response performance by maintaining a clean state. Such pH electrodes cannot be realized with commercially available pH-responsive glass electrode. As for the development of a Li-free electronically conductive glass electrode having a self-cleaning function based on anti-fouling property (hydrophobicity), we developed Fe2O3-Bi2O3-GeO2 glasses with higher contact angle with water compared with the  previously reported Fe2O3-Bi2O3-B2O3 glasses. In addition, the stainless electrode sol-gel coated with transition metal oxide showed high pH sensitivity and fast pH response. This stainless electrodes with excellent processability are candidate for a disposable pH electrode.", "subitem_description_type": "Abstract"}]}, "item_8_description_5": {"attribute_name": "内容記述", "attribute_value_mlt": [{"subitem_description": "2015年度～2017年度科学研究費補助金(基盤研究(C))研究成果報告書", "subitem_description_type": "Other"}]}, "item_8_description_64": {"attribute_name": "科研費番号", "attribute_value_mlt": [{"subitem_description": "15K06439", "subitem_description_type": "Other"}]}, "item_8_full_name_2": {"attribute_name": "著者（ヨミ）", "attribute_value_mlt": [{"nameIdentifiers": [{"nameIdentifier": "43391", "nameIdentifierScheme": "WEKO"}], "names": [{"name": "ハシモト, タダノリ", "nameLang": "ja-Kana"}]}, {"nameIdentifiers": [{"nameIdentifier": "43392", "nameIdentifierScheme": "WEKO"}], "names": [{"name": "イシハラ, アツシ", "nameLang": "ja-Kana"}]}, {"nameIdentifiers": [{"nameIdentifier": "43393", "nameIdentifierScheme": "WEKO"}], "names": [{"name": "ナス, ヒロユキ", "nameLang": "ja-Kana"}]}]}, "item_8_publisher_30": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "三重大学"}]}, "item_8_text_31": {"attribute_name": "出版者（ヨミ）", "attribute_value_mlt": [{"subitem_text_value": "ミエダイガク"}]}, "item_8_text_65": {"attribute_name": "資源タイプ（三重大）", "attribute_value_mlt": [{"subitem_text_value": "Kaken / 科研費報告書"}]}, "item_8_version_type_15": {"attribute_name": "著者版フラグ", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_970fb48d4fbd8a85", "subitem_version_type": "VoR"}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "橋本, 忠範", "creatorNameLang": "ja"}], "nameIdentifiers": [{"nameIdentifier": "43388", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "石原, 篤", "creatorNameLang": "ja"}], "nameIdentifiers": [{"nameIdentifier": "43389", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "那須, 弘行", "creatorNameLang": "ja"}], "nameIdentifiers": [{"nameIdentifier": "43390", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2020-01-22"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "2019RP0080.pdf", "filesize": [{"value": "2.9 MB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_note", "mimetype": "application/pdf", "size": 2900000.0, "url": {"label": "2019RP0080", "url": "https://mie-u.repo.nii.ac.jp/record/13301/files/2019RP0080.pdf"}, "version_id": "2fb2fbe4-b473-48ed-a823-8b5b3c2331c0"}]}, "item_keyword": {"attribute_name": "キーワード", "attribute_value_mlt": [{"subitem_subject": "pH応答ガラス", "subitem_subject_scheme": "Other"}, {"subitem_subject": "セルフクリーニング機能", "subitem_subject_scheme": "Other"}, {"subitem_subject": "メンテナンスフリー", "subitem_subject_scheme": "Other"}, {"subitem_subject": "撥水性", "subitem_subject_scheme": "Other"}, {"subitem_subject": "電子伝導ガラス", "subitem_subject_scheme": "Other"}, {"subitem_subject": "ゾル-ゲルコーティング", "subitem_subject_scheme": "Other"}, {"subitem_subject": "ステンレス電極", "subitem_subject_scheme": "Other"}, {"subitem_subject": "ディスポーザブル電極", "subitem_subject_scheme": "Other"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "jpn"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "research report", "resourceuri": "http://purl.org/coar/resource_type/c_18ws"}]}, "item_title": "セルフクリーニングpH電極ならびにディスポーザブルpH電極の開発", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "セルフクリーニングpH電極ならびにディスポーザブルpH電極の開発", "subitem_title_language": "ja"}, {"subitem_title": "Development of self-cleaning pH electrodes and disposable pH electrodes", "subitem_title_language": "en"}]}, "item_type_id": "8", "owner": "15", "path": ["1692685142618"], "permalink_uri": "http://hdl.handle.net/10076/00018920", "pubdate": {"attribute_name": "PubDate", "attribute_value": "2020-01-22"}, "publish_date": "2020-01-22", "publish_status": "0", "recid": "13301", "relation": {}, "relation_version_is_last": true, "title": ["セルフクリーニングpH電極ならびにディスポーザブルpH電極の開発"], "weko_shared_id": -1}