| Item type |
学術雑誌論文 / Journal Article(1) |
| 公開日 |
2010-03-02 |
| タイトル |
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|
タイトル |
Ag2O-Na2O-B2O3系混合カオチンガラスの電気泳動 |
|
言語 |
ja |
| 言語 |
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|
言語 |
jpn |
| 資源タイプ |
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|
資源タイプ識別子 |
http://purl.org/coar/resource_type/c_6501 |
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資源タイプ |
journal article |
| 著者 |
松下, 和正
伊藤, 増夫
神谷, 寛一
作花, 済夫
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| 抄録 |
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内容記述タイプ |
Abstract |
|
内容記述 |
The electrical conductivities of glasses in the Ag2O-B2O3, Na2O-B2O3 and Ag2O-Na2O-B2O3 (Ag2O + Na2O = 27.4 mol% in average) systems have been determined over the temperature range from room temperature to about 400℃ using both d.c. and a.c. measurements. The temperature dependence of the electrical conductivities of the glasses could be described by the Rasch-Hinrichsen equation : σ = σ0exp (-ΔH/RT) The Ag2O-B2O3 glasses showed higher conductivity and lower activation energy for conduction than the Na2O-B2O3 glasses did. The mixed cation effect was observed in the Ag2O-Na2O-B2O3 system ; a minimum in the electrical conductivity and a maximum in the activation energy were found around the Ag/(Ag + Na) ratio of 1/5 on the property-composition curves. A minimum in the dielectric constant was also found. The magnitude of the mixed cation effect in the silver-containing system was, however, considerably smaller than that found in mixed-alkali glasses involving Li, Na, K or Cs ions. The electrical conductivity was much greater and the activation energy was smaller for the Ag2O-Na2O-B2O3 glasses of the composition range of Ag/(Ag + Na)>1/5, in which Ag+ ions are dominant current carries, than for the single cation Ag2O-B2O3 glasses of the same Ag2O content. This indicates that the mobility of Ag+ ions is increased on addition of Na+ ions in contrast with that of the alkali ions in mixed-alkali glasses which remains the same or is decreased on addition of alkali ions of the other type. Such behavior of the mobility of Ag+ ions was discussed by assuming the formation of Ag+ ion clusters which results in the shortening of the jump distances required for the migration of Ag+ ions. |
| 書誌情報 |
窯業協會誌 = Journal of the Ceramic Association, Japan
巻 84,
号 974,
p. 496-508,
発行日 1976-10-01
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| ISSN |
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収録物識別子タイプ |
PISSN |
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収録物識別子 |
0009-0255 |
| 書誌レコードID |
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収録物識別子タイプ |
NCID |
|
収録物識別子 |
AN00245650 |
| 権利 |
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|
権利情報 |
社団法人日本セラミックス協会 |
| 権利 |
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|
権利情報 |
本文データは学協会の許諾に基づきCiNiiから複製したものである |
| フォーマット |
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|
内容記述タイプ |
Other |
|
内容記述 |
application/pdf |
| 著者版フラグ |
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|
出版タイプ |
VoR |
|
出版タイプResource |
http://purl.org/coar/version/c_970fb48d4fbd8a85 |
| その他のタイトル |
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|
値 |
The electric conduction in mixed cation glasses of the Ag2O-Na2O-B2O3 system |
| 出版者 |
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|
出版者 |
窯業協会 |
| 関係URI |
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|
関連名称 |
http://ci.nii.ac.jp/naid/110002315848 |
| 資源タイプ（三重大） |
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|
値 |
Journal Article / 学術雑誌論文 |
40A11430.pdf (1.2 MB)
